![]() This really was such a fun family activity.Get some fresh air with these 5 DIY kites kids will love to fly. Perseverance paid off! Theo was SO proud when he finally got it off the ground! Somehow our newspaper kite survived crashing and being dragged around the ground many times. Here’s Lucy and Theo about to try to get Lucy’s plastic trash bag kite up! Kite flying required all kinds of teamwork. We made all kinds of adjustments to get our kites into the air!įlying our homemade kites was one of my favorite memories from this summer! We literally ran around for hours working on getting our kites up in the air! Tip: Be sure to bring some scissors, tape, and string with you when you go out to fly your kite. Use ribbon to create a tail for your kite. (The other string along the bottom was just an extension of when I wrapped the string around the frame. Here you can see the brindle string running along to the top edge of the dowel rod. (We started by tying the string about 1/3 of the way down the brindle and adjusted it as we flew our kite.) Tie your flying string to this brindle string to fly your kite. (Use some tape to keep it secure.) This is the brindle of your kite. Tie one end of the string into the top hole and one end into the bottom hole. Poke holes into the top and bottom points of the kite. Fold the edges of the newspaper over the string and tape them down securely.ħ. Cut a piece of string 24 inches long. Cut about one inch outside the frame to make your newspaper the same shape.Ħ. Place a large sheet of newspaper on the floor. (You can also use a plastic trash bag.)ĥ. Now that your frame is done, it’s time to add your newspaper. Place some masking tape over the string to secure your dowels.Ĥ. W rap string all the way around the kite, making sure it goes right into the notches. You’ll want them all parallel to the floor your sticks are on so that you can later wrap string around the frame. Pay attention to the notches at the end of each dowel. Use your string to wrap the dowels together where they meet. Place the smaller dowel across this mark to form a ‘t’ shape. Lay the 24 inch dowel vertical and measure 6 inches from the top. (For safety reasons, I did this myself.)ģ. Use your handsaw to make notches in both ends of your two wooden dowels. (The kids helped me measure the dowels with a yardstick, and I cut them myself with the saw.)Ģ. ![]() Start by cutting your wooden dowels to the correct lengths- 24 inches and 20 inches.
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![]() I w momencie bandyckiej napaści rosji na Ukrainę przesiadłem się na inny menadżer haseł, a tego usunąłem. Jeden szkopuł, który od kilku lat coraz bardziej mnie martwił. Używałem na PC, również jako wtyczka do przeglądarki i na Androidzie w smartfonie. () Krzysztof Żebrowski: Używałem już kilka lat.I want you to support to Chrome's login form for the basic authentication. Bestimmt kann man den Zeitraum verlängern, aber wo? Was mich auch sehr stört - nach 3 sekunden verlangt die App erneut, dass ich mich einlogge. Also war das so`ne Idee.Aber nun werde ich wohl alle wieder deinstallieren. ![]() Google selbst setzte sie nur manchmal ein, Lastpass nur gegen Vertrag dann auch auf Android. () Lore Potlin: Leider wird kein Passwort auf irgenteiner Website automatisch eingegeben, obwohl ich die Haken, soweit gesehen alle gesetzt habe.() Jair: Muy fácil de usar y con aplicación desde pc va excelente.() Jan Flo: The desktop app and web browser extension can't synchronize my passwords.So you won't rate this 1 star to avoid misjudge and to mislead other users) (Also read their "help" page if you need help with anything, () MikeGamer Playz: After time after time of searching, I've finally found the password manager that was no "pro" or "paid" version, I really recommend that you try it.The developers tell you to download from the play store, but it does not actually do anything, and doesn't grant any of the features. () Mark Menegatti ᴏsᴀ: No available for chromebook.Ottimo lavoro, grazie per aver reso disponibile SafeInCloud ! La vera meraviglia è la sincronizzazione perfetta con il cloud personale/aziendale a scelta (OneDrive, Google Drive, DropBox, Box, Dav (spazio virtuale presente su server, con agenda, calendario, etc.), o impostare manualmente altro tipo di virtual storage in questo modo, installando l'applicazione su ogni dispositivo che si possiede, è possibile accedere ai dati mantenendoli al sicuro. Si possono memorizzare ed utilizzare per il riempimento automatico, tramite web extension (esistente per tutti i browsers), anche carte di credito e account di home banking, numeri di conto corrente (IBAN + BIC/SWIF), PIN di accesso, indirizzo web e credenziali di gestione della propria rete LAN e router, di dispositivi per la domotica, oltre a tutti i dati inseribile tramite personalizzazione del nome e della tipologia di tutti i campi di input. () ۷εηⲇεⲧⲧⲁ Ⲥⲁ༩ⲧεے: Migliore app di management & storage di password, ma non solo: tutti i dati sensibili ed importanti, ricorrenti da inserire nei moduli vari, che alla fine ci si dimentica sempre, pur dovendoli inserire quotidianamente o in ogni caso molto spesso.Tato aplikace s tím umí výborně pracovat. Je potřeba je mít naprosto náhodná a nezapamatovatelná. S tím množstvím kdejakých účtů a přihlašovacích údajů už z bezpečnostních důvodů člověk opravdu nemůže používat jednoduchá a/nebo zapamatovatelná hesla. () Zdeněk Lehocký: Perfektní appka a rozšíření do prohlížeče.() DJ P: No support for Chrome OS or Chromebooks. ![]() ¿Para cuando en Linux, sabiendo que una aplicación con excelente potencial? Me quedo con Bitwarder como extensión, ya que no necesita dependencias de aplicaciones de Escritorio. No funciona la extensión (Chrome/Firefox) en Linux y Windows, necesita de la aplicación de Escritorio funcionando en segundo plano para poder funcionar. Una App de Escritorio para Linux estaría muy bien así como KeePass y Bitwarden.
![]() ![]() Edward Norton played Bruce Banner and Tyler played his love interest in The Incredible Hulk (2009). ![]() On March 27, 2023, The Hollywood Reporter revealed Liv Tyler’s Elizabeth “Betty” Ross return. Tim Blake Nelson, The Leader of The Incredible Hulk, is returning to the MCU.ĭanny Ramirez (Joaquin Torres) and Carl Lumbly (Isiah Bradley) reprise their Falcon and Winter Soldier roles.ĭeadline reports that Xosha Roquemore will debut in the MCU with Shira Haas as Sabra. “Thunderbolt” Ross after William Hurt’s death. Harrison Ford will play General Thaddeus E. Captain America 4 Cast Members: Who Are in It?Īnthony Mackie will play Captain America after Avengers: Endgame. 3, and The Marvels, all of which will premiere in 2023. Next up on the MCU schedule is Black Panther: Wakanda Forever, which will be released later this year, followed by Ant-Man and the Wasp: Quantum Mania, Guardians of the Galaxy Vol. New World Order will be directed by Julius Onah, whose credits include the massively terrifying The Cloverfield Paradox and the highly regarded Luce. Captain America 4 Release Date: When is It Coming Out?Īccording to sources, On May 3, 2024, Captain America 4-the second-to-last film of Phase Five of the MCU, after Thunderbolts-will be released. Wilson has complete and proud ownership of the shield after this series has set the scenario for Captain America. ![]() The Falcon and the Winter Soldier was a small-screen release that followed the ongoing exploits of Wilson (Anthony Mackie) and Bucky Barnes (Sebastian Stan). It began with a late-arriving solo outing for Black Widow, continued with the introduction of martial arts in Shang-Chi, recruited an entirely new team in The Eternals, featured a trio of wall-crawlers in Spider-Man: No Way Home, and that’s not even mentioning Doctor Strange, Thor, and *gestures wildly* all the Disney+ content. Phase Four of the Marvel Cinematic Universe has concluded. The release date, cast, and plot of Captain America 4, Anthony Mackie’s first solo outing in the MCU, are all listed here. ![]() ![]() One good shot and you can work all day without a shirt! “All Mighty 140” Shine proves that even at an intense proof, and 140 proof is intense, a premium moonshine can still have a smooth-as-silk, creamy corn and butter taste that is unforgettable. THIS IS HOW REAL SHINE TASTES– RIGHT OFF THE STILL. Instead of cutting it down to 100 proof, we just collect the hearts from our copper still at 140 proof and bottle it. We just mix it, let it ferment and distill it. It’s the same corn, sugar and water, and just like “All Purpose”, we don’t cook the mash. By morning, we had decided to create the premium version of our shine, and “All Mighty 140” was born. A sizable number of visitors also started requesting an even higher proof version of our Shine, and we pondered that request as we collected the hearts from the still one evening. At 100 proof, it was a pleasing nod to the traditions and heritage of Tennessee and the whole South.įolks appreciated the authenticity of the recipe, and seemed to enjoy being taken back in time to the simpler ways with each sip. Immediately popular, it showed how a high-proof spirit made from only Giles County white corn, sugar and pure water could reach the hearts of locals and visitors alike. All Mighty Moonshineīig Machine Distillery first offered their “All Purpose Shine” to the public in 2013. We invite you to taste our Southern heritage whiskey and to appreciate our quality and attention to detail. These selections or cuts are the reason we believe that the traditional small batch process is superior to the continuous distillation process often used these days. ![]() No “heads” or “tails” make it into our barrels. ![]() Our chief distiller, Clayton Cutler, makes judicious distiller’s cuts during each distillation and only the select “hearts” of the run are set aside for aging. Our mash bill is locally grown white corn, wheat and malted barley which is fermented and then copper pot distilled. This signature step serves to differentiate Clayton James Tennessee Whiskey from all other Tennessee Whiskies. Instead, we allow our spirits to acquire unique sweet maple smokiness from the charcoal. Since our new whiskey is only “hearts”, we don’t need to use charcoal filtering to remove impurities or take off a harsh edge. ![]() We use the Lincoln County Process quite a bit differently than others. This spirit dwells in sugar maple charcoal, the Lincoln County Process, before entering the new, charred white oak barrels for aging. ![]() ![]() ![]() ![]() ![]() Marginal note: Conventions on diplomatic relations and consular relations 3 (1) Articles 1, 22 to 24 and 27 to 40 of the Vienna Convention on Diplomatic Relations, and Articles 1, 5, 15, 17, 31 to 33, 35, 39 and 40, paragraphs 1 and 2 of Article 41, Articles 43 to 45 and 48 to 54, paragraphs 2 and 3 of Article 55, paragraph 2 of Article 57. Article 74: Diplomatic and consular relations and the conclusion of treaties. Avoiding controversial issues such as diplomatic asylum and focusing on permanent envoys rather than on ad hoc representatives or other internationally protected persons, the convention accorded immunity from criminal. PART I Foreign Diplomatic Missions and Consular Posts. Article 55: Reduction of the parties to a multilateral treaty below the. This codification of public international law has of course served to clarify pre-existing rules but it has at the same time made it possible to bring these rules up to date so as to meet better the new requirements of the community of States-the society which is governed by that law and which has undergone significant changes in the last few decades. The Vienna Convention on Diplomatic Relations (1961) restricted the privileges granted to diplomats, their families, and staff. The Conference on the Law of Treaties held at Vienna in 19, like the other important United Nations conferences on the codification of international law (Geneva Conferences on the Law of the Sea of 19, Vienna Conference on Diplomatic Intercourse and Immunities of 1961 and Vienna Conference on Consular Relations of 1963), formulated and adopted a Convention on the basis of a draft which was the collective work of the International Law Commission (ILC) of the United Nations, carried out under the guidance of a Special Rapporteur.We have thus been witnessing since 1958 the interesting process of the reduction into treaty law of a substantial part of the customary international law of peace if this period is compared with the centuries that went before, the transformation of unwritten rules into written law which has thus taken place appears remarkably fast. The Vienna Convention on Diplomatic Relations of 1961 is an international treaty that defines a framework for diplomatic relations between independent. The States Parties to the present Protocol and to the Vienna Convention on Diplomatic Relations, hereinafter referred to as the Convention, adopted by the United Nations Conference held at. ![]() ![]() ![]() The equipotential surfaces form ellipsoidal shells around the center of the planet, while the surface of any ellipsoidal shell is always perpendicular to the effective gravitational acceleration at any point. An equipotential surface is a surface where the effective gravitational acceleration has the same magnitude everywhere. This has to do with the fact that the earth is mostly liquid and the surface of any liquid always is level to an equipotential surface. ![]() Why is it that the ellispoid has a shape just right so that the effective acceleration is everywhere perpendicular to the surface? This implies that the pure gravitational acceleration generally does not act perpendicular to the surface. The ellipsoid has just such a shape, so that the effective gravitational acceleration acts everywhere perpendicular to the surface of the ellipsoid. The effective gravitational acceleration at any point on earth is the vector sum of the pure gravitational acceleration due to gravity plus the centrifugal acceleraion due to earth's rotation. So the formulas to compute the effective gravitational acceleration on a point on earth is much more complicated. This means that the pure gravitational acceleration is dependent on the latitude and there is another component acting against gravity: the centrifugal acceleration a C, which is also dependent on the latitude. Now, the earth is not a perfect sphere but an oblate ellipsoid of revolution, also called an oblate spheroid, and is rotating with the angular speed ω around its minor axis. On a perfect non-rotating sphere the gravitational acceleration for each point on the surface of the sphere is according to Newton: It is prefered to use the gravitational acceleration instead of the force, because the acceleration is the same for any mass m, so m is not contained in the formula. Gravity can also be expressed as a gravitational acceleration g = F / m. On each point P on earth there is a gravitational force F acting on a mass m down to the center of the earth. This radius changes with position because the earth is an ellipsoid. R h: Distance from the center of the earth to to the point P h at altitude Alt, see (7). Depends on the rotational speed ω or the rotational period T and the radius r φ where r φ is the perpendicular distance of the point P h from the earth axis. V h: Tangential velocity at altitude Alt and at point P h. The radius r φ is the perpendicular distance of the point P h from the earth axis. This is dependent on the rotational speed or rotation period T and the radius r φ for the latitude Lat. the earth radius at latitude Lat plus the altitude Alt.Ī hC: Centrifugal acceleration at altitude Alt at point P h, see (19). Depending on the mass M of the earth and the distance R h from the center of the earth, i.e. G hG: Pure gravitational acceleration at altitude Alt at point P h, see (21). This is the vectorial sum of pure gravitational acceleration g hG and centrifugal acceleration a hC. G h: Effective gravitational acceleration at altitude Alt at point P h, see (17). W h: Weight of the test mass as displayed on the scale at altitude Alt at point P h. R o: Distance from the center of the earth to to the point P, see (6). Depends on the rotational speed ω or the rotational period T and the radius r φ where r φ is the perpendicular distance of the point P from the earth axis. V 0: Tangential velocity at the surface at point P. On the poles this radius is 0, on the equator it is equal to the radius of the earth at that location. The radius r φ is the perpendicular distance of the point P from the earth axis. ![]() Depending on the mass M of the earth and the distance R o from the center of the earth.Ī oC: Centrifugal acceleration on earth's surface at point P, see (11). G oG: Pure gravitational acceleration on earth's surface at point P, see (14). This corresponds to the vectorial sum of pure gravitational acceleration g oG and centrifugal acceleration a oC. G o: Effective gravitational acceleration on earth's surface at point P, see (9). W o: Weight of the test mass displayed on the scale at sea level at point P. ![]() ![]() ![]() The main reason they have fewer resources available is that they are designed for a single purpose, so they only have one task to perform. Generally, specific purpose devices have far fewer resources than what we expect from general-purpose devices. One can develop projects, watch a film, compose music, and much more. Their purpose depends on what the user wants to do with them. In contrast, general-purpose devices, such as computers, mobile phones, and smartwatches are machines that can perform any kind of task ― from writing an email to watching a movie. In these examples, only one purpose can be identified ― in the case of a microwave oven, the device will only heat food and certainly not show a film. As an example, devices that are designed for a specific purpose are household appliances, home automation, cameras, printers, heating systems, etc. We can identify two broad categories in everyday devices: Those that are designed for a specific purpose and those called general-purpose. To begin analyzing firmware, it is necessary to first introduce a few notions about embedded devices: What are they? and Why have they been called that? Now, let’s begin here by exploring an IP camera. Starting from higher level details, then onto the lowest level details, and then delving into the user interface, we will explain how the camera was created and developed. In this series of articles, which will be published on a weekly basis, we will be taking an in-depth look at the technical functioning of an IP camera from the company Reolink ― in an effort to better understand the potential risks of an IoT device. For the time being, it appears that many IoT manufacturers simply ignore this. Issues related (more broadly) to cybersecurity and (more specifically) your privacy are imperative to avoid, so that elements related to your private life are not exposed. However, this evolution has some disadvantages: The perennial need to be connected to the Internet and an increase in the potential attack surface. The emergence of these next generation technologies has driven the home automation evolution from simple light bulbs to cloud-connected printers, smart refrigerators, etc. Embedded devices continue to increase in popularity and one category, in particular, that has become en vogue as of late is the Internet of Things (IoT). ![]() ![]() ![]() It is a shredded foam-filled chair that never goes flat but will require up to 48 hours for expanding to its full glory, thanks to the homegrown technology from Grand Rapids, MI. Since 10% of their profits all go to charity for kids, you can feel good about your purchase knowing that Big Joe is a company that cares.The Big Joe Fuf W/Liner is a patented giant bean bag chair that is currently making waves. Don’t waste your time or money on knock-offs pretending to be the same quality as Big Joe. The Big Joe XXL Fuf Foam chair is one of the highest-quality bean bag chairs available on the market right now. 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Fuf chair facebook twitter linkedin pinterest Big Joe Fuf Small Beanbag Chair Desert Rose Plush. ![]() ![]() ![]() Textbook content produced by OpenStax is licensed under a Creative Commons Attribution License. We recommend using aĪuthors: Paul Flowers, Klaus Theopold, Richard Langley, William R. Use the information below to generate a citation. Then you must include on every digital page view the following attribution: If you are redistributing all or part of this book in a digital format, ![]() Then you must include on every physical page the following attribution: If you are redistributing all or part of this book in a print format, Want to cite, share, or modify this book? This book uses the This predictive strategy and related calculations are demonstrated in the next few example exercises. Q sp K sp: the reaction proceeds in the reverse direction (solution is supersaturated precipitation will occur) For the specific case of solubility equilibria: The comparison of Q sp to K sp to predict precipitation is an example of the general approach to predicting the direction of a reaction first introduced in the chapter on equilibrium. If the ion concentrations yield a reaction quotient greater than the solubility product, then precipitation will occur, lowering those concentrations until equilibrium is established ( Q sp = K sp). If the concentrations of calcium and carbonate ions in the mixture do not yield a reaction quotient, Q sp, that exceeds the solubility product, K sp, then no precipitation will occur. Consider, for example, mixing aqueous solutions of the soluble compounds sodium carbonate and calcium nitrate. It is important to realize that this equilibrium is established in any aqueous solution containing Ca 2+ and CO 3 2– ions, not just in a solution formed by saturating water with calcium carbonate. Solution ( a ) AgI ( s ) ⇌ Ag + ( a q ) + I − ( a q ) K sp = ( b ) CaCO 3 ( s ) ⇌ Ca 2+ ( a q ) + CO 3 2− ( a q ) K sp = ( c ) Mg ( OH ) 2 ( s ) ⇌ Mg 2+ ( a q ) + 2OH − ( a q ) K sp = 2 ( d ) Mg ( NH 4 ) PO 4 ( s ) ⇌ Mg 2+ ( a q ) + NH 4 + ( a q ) + PO 4 3− ( a q ) K sp = ( e ) Ca 5 ( PO 4 ) 3 OH ( s ) ⇌ 5Ca 2+ ( a q ) + 3PO 4 3− ( a q ) + OH − ( a q ) K sp = 5 3 ( a ) AgI ( s ) ⇌ Ag + ( a q ) + I − ( a q ) K sp = ( b ) CaCO 3 ( s ) ⇌ Ca 2+ ( a q ) + CO 3 2− ( a q ) K sp = ( c ) Mg ( OH ) 2 ( s ) ⇌ Mg 2+ ( a q ) + 2OH − ( a q ) K sp = 2 ( d ) Mg ( NH 4 ) PO 4 ( s ) ⇌ Mg 2+ ( a q ) + NH 4 + ( a q ) + PO 4 3− ( a q ) K sp = ( e ) Ca 5 ( PO 4 ) 3 OH ( s ) ⇌ 5Ca 2+ ( a q ) + 3PO 4 3− ( a q ) + OH − ( a q ) K sp = 5 3 Ĭheck Your LearningWrite the dissolution equation and the solubility product for each of the following slightly soluble compounds:ĬaCO 3 ( s ) ⇌ Ca 2+ ( a q ) + CO 3 2− ( a q ) K s p = 8.7 × 10 − 9 CaCO 3 ( s ) ⇌ Ca 2+ ( a q ) + CO 3 2− ( a q ) K s p = 8.7 × 10 − 9 (e) Ca 5(PO 4) 3OH, the mineral apatite, a source of phosphate for fertilizers (d) Mg(NH 4)PO 4, magnesium ammonium phosphate, an essentially insoluble substance used in tests for magnesium (c) Mg(OH) 2, magnesium hydroxide, the active ingredient in Milk of Magnesia (b) CaCO 3, calcium carbonate, the active ingredient in many over-the-counter chewable antacids (a) AgI, silver iodide, a solid with antiseptic properties Write the dissolution equation and the solubility product expression for each of the following slightly soluble ionic compounds: Writing Equations and Solubility Products For example, a saturated solution of silver chloride is one in which the equilibrium shown below has been established. A solute with finite solubility can yield a saturated solution when it is added to a solvent in an amount exceeding its solubility, resulting in a heterogeneous mixture of the saturated solution and the excess, undissolved solute. Recall from the chapter on solutions that the solubility of a substance can vary from essentially zero ( insoluble or sparingly soluble) to infinity ( miscible). This section applies previously introduced equilibrium concepts and tools to systems involving dissolution and precipitation. An understanding of the factors affecting compound solubility is, therefore, essential to the effective management of these processes. These equilibria underlie many natural and technological processes, ranging from tooth decay to water purification. Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. Carry out equilibrium computations involving solubility, equilibrium expressions, and solute concentrations.Write chemical equations and equilibrium expressions representing solubility equilibria.By the end of this section, you will be able to: ![]() ![]() ![]() Even animals exhibited the phenomenon of childhood amnesia according to some studies. ![]() Sigmund Freud coined the term ‘Infantile Amnesia’ to describe the lack of recall of childhood memories after conducting therapy sessions with mentally ill patients.Five years later, Henri and Henri (1900) reported that their study participants could not recall memories before the age of 2-4 years.In 1895, Caroline Miles first discovered the phenomena of childhood amnesia.Whereas others, think 2-7 years of age is a more accessible age bracket. Some researchers consider 3-4 years as the age when we can retrieve our earliest memory. The exact age of onset of childhood amnesia is unclear. Some people remember fragments of when they were one year old, but as they get older, they start to forget them. Memories of situations or events before the age of 2-4 years are usually vague and hazy. No one can accurately remember the first three years of their life. Most people can recall memories from their childhood but only to a certain point. This is because of a phenomenon called childhood amnesia. Chances are you can remember a few images, how you acted, and one or two words, but not the entire context or the sequence of events that followed. Visualize the context and try to recall the exact details. Possible Explanations for why we forget our childhoodĬan you recall your childhood memories? What is your earliest childhood memory? Can you remember when you took your first step? or said your first word? Take some time and think about what you can remember when you were between the ages of 2-4 years old. ![]() |
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